Design and Optimization of Copper Zinc Tin Sulfide (CZTS) Thin Film Solar Cell
Abstract
In this research work, we show how to develop and simulate highly efficient Copper Zinc Tin Sulfide (CZTS) based thin film solar cell with dual-heterojunction. A dual-heterojunction is created when Copper Zinc Tin Sulfide (CZTS) forms a p-n junction with a window layer and another p-p+ connection with a highly doped back surface Field (BSF) layer. The simulation was performed with SCAPS-1D software, which uses known experimental physical parameters. The results exhibit the best PCE as high as 45.08 % with Voc=1.346 V, Jsc=41.59 mA/cm2, FF=80.49 % for dual heterojunction structure of n-ZnSe/p-CZTS/p+-CGS/Ni with a good level of temperature coefficient (TC) is found to be (-0.069 %/?C). The simulation results show that the Power Conversion Efficiency (PCE) of the single heterojunction n-ZnSe/p-CZTS/Ni solar cell may reach 19.62%, while the PCE of the dual heterojunction solar cell can reach 45.08 %.
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J. Collier, S. Wu and D. Apul, "Life cycle environmental impacts from CZTS (copper zinc tin sulfide) and Zn3P2 (zinc phosphide) thin film PV (photovoltaic) cells," Energy, pp. 314-321, 2014.
M. A. Green, Y. Hishikawa, E. D. Dunlop, D. H. Levi, J. Hohl-Ebinger and A. W. Ho-Baillie, "Solar cell efficiency tables (version 52)," Prog Photovolt Res Appl, vol. 26, p. 427–436, 2018.
R. Kishore, S. Singh and B. Das, "PECVD grown silicon nitride AR coatings on polycrystalline silicon solar cells," Solar Energy Materials and Solar Cells, vol. 26, no. 1-2, pp. 27-35, 1992.
G. Willeke, H. Nussbaumer, H. Bender and E. Bucher, "A simple and effective light trapping technique for polycrystalline silicon solar cells," Solar Energy Materials and Solar Cells, vol. 26(4), pp. 345-356, 1992.
M. Edoff, "Thin film solar cells: research in an industrial perspective," Ambio, vol. 41(Suppl 2), pp. 112-118, 2012.
H. Uda, S. Ikegami and H. Sonomura, "Te—metal contact on evaporated CdTe film for a CdS/CdTe solar cell.," Solar energy materials and solar cells, vol. 35, pp. 293-298, 1994.
N. K. Das, S. F. U. Farhad, J. Chakaraborty, A. K. S. Gupta, M. Dey and M. Al-Mam, "Structural and optical properties of RF-sputtered CdTe thin films grown on CdS: O/CdS bilayers," International Journal of Renewable Energy Research, vol. 10(1), pp. 293-302, 2020.
S. A. Razi, N. K. Das, S. F. U. Farhad and M. A. M. Bhuiyan, "Influence of the CdCl2 solution concentration on the properties of CdTe thin films.," International Journal of Renewable Energy Research (IJRER), vol. 10(2), pp. 1012-1020, 2020.
M. Dey, M. A. Matin, N. K. Das and M. Dey, "Germanium telluride as a BSF material for high efficiency ultra-thin CdTe solar cell," in 9th International Forum on Strategic Technology (IFOST),IEEE, Cox's Bazar, Bangladesh, 2014.
S. Bhattacharjee, M. Hassan, N. K. Das and M. Dey, "Design and Optimization of Copper Antimony Sulfide Thin Film Solar Cell," International Journal of Renewable Energy Research (IJRER), vol. 13(3), pp. 1398-1405, 2023 Sep 27.
M. Dey, R. Chakma, N. Rahman, M. Dey, N. K. Das, A. K. S. Gupta, M. A. Matin and N. Amin, "Study of ultra-thin and stable alsb solar cell with potential copper telluride BSF," in In2017 IEEE Region 10 Humanitarian Technology Conference (R10-HTC) (pp. 811-814). IEEE, Dhaka, Bangladesh, 2017 Dec 21.
M. Dey, J. Ferdous, S. B. Afsar, M. Dey and N. K. Das, "Design and Optimization of Efficient FeS2 Solar Cell," in 2019 International Conference on Electrical, Computer and Communication Engineering (ECCE), IEEE, Cox'sBazar, Bangladesh, 2019.
E. M. K. I. Ahamed, N. K. Das, A. K. S. Gupta, M. N. I. Khan, M. A. Matin and N. Amin, "Structural and optical characterization of As-grown and annealed ZnxCd1-xS thin-films by CBD for solar cell applications," International Journal of Renewable Energy Research, vol. 10(3), pp. 1464-1474, 2020 Sep 23.
M. Dey, M. Dey, S. Alam, A. K. S. Gupta, N. K. Das, M. A. Matin and N. Amin, "Design of ultra-thin CZTS solar cells with indium selenide as buffer layer," in 2017 International Conference on Electrical, Computer and Communication Engineering (ECCE) (pp. 946-950), IEEE, Cox's Bazar, Bangladesh, 2017.
M. Dey, M. Dey, S. Alam, N. K. Das, M. A. Matin and N. Amin, "Study of molybdenum sulphide as a novel buffer layer for CZTS solar cells," in 3rd International Conference on Electrical Engineering and Information Communication Technology (ICEEICT) (pp. 1-4). IEEE, Dhaka, Bangladesh, 2016.
M. Dey, M. Dey, T. Biswas, S. Alam, N. K. Das, M. A. Matin and N. Amin, "Modeling of Cu2ZnSnS4 solar cells with Bismuth Sulphide as a potential buffer layer," in 5th International Conference on Informatics, Electronics and Vision (ICIEV), pp. 1095-1098. IEEE, Dhaka, Bangladesh, 2016.
U. Saha and M. K. Alam, "Proposition of an environment friendly triple junction solar cell based on earth abundant CBTSSe/CZTS/ACZTSe materials," physica status solidi (RRL)–Rapid Research Letters, vol. 12(1), p. 1700335, 2018.
M. Ravindiran and C. Praveenkumar, "Status review and the future prospects of CZTS based solar cell–A novel approach on the device structure and material modeling for CZTS based photovoltaic device," Renewable and Sustainable Energy Reviews, vol. 94, pp. 317-29, 2018 Oct 1.
H. Katagiri, K. Saitoh, T. Washio, H. Shinohara, T. Kurumadani and S. Miyajima, "Development of thin film solar cell based on Cu2ZnSnS4 thin films. ,, pp.," Solar Energy Materials and Solar Cells, Vols. 65(1-4), pp. 141-148, 2001.
Y.-P. Lin, Y.-F. Chi, T.-E. Hsieh, Y.-C. Chen and K.-P. Huang, "Preparation of Cu2ZnSnS4 (CZTS) sputtering target and its application to the fabrication of CZTS thin-film solar cells," Journal of Alloys and Compounds, vol. 654, pp. 498-508, 2016.
J. Henry, K. Mohanraj and G. Sivakumar, "Electrical and optical properties of CZTS thin films prepared by SILAR method," Journal of Asian Ceramic Societies , vol. 4(1), p. 81–84, 2016.
Crovetto, M. K. Huss-Hansen and O. Hansen, "How the relative permittivity of solar cell materials influences solar cell performance," Solar Energy, vol. 149, pp. 145-150, 2017 Jun 1.
S. Chen, X. G. Gong, A. Walsh and S. Wei, "Crystal and electronic band structure of Cu2ZnSnX4 (X= S and Se) photovoltaic absorbers: First-principles insights.," Applied Physics Letters, vol. 94(4), 2009.
M. Kumar, A. Dubey, N. Adhikari, S. Venkatesan and Q. Qiao, "Strategic review of secondary phases, defects and defect-complexes in kesterite CZTS–Se solar cells," Energy & Environmental Science, vol. 8(11), pp. 3134-3159, 2015.
K. Rudisch, Y. Ren, C. Platzer-Björkman and J. Scragg, "Order-disorder transition in B-type Cu2ZnSnS4 and limitations of ordering through thermal treatments," Applied physics letters, vol. 108(23), 2016 Jun 6.
J. Chantana, H. Arai, Y. Niizawa and T. Minemoto, "Ohmic-like contact formation at the rear interface between Cu (In, Ga) Se2 and ZnO: Al in a lift-off Cu (In, Ga) Se2 solar cell," Thin Solid Films, vol. 616, pp. 17-22, 2016.
S. P. Bremner, M. Y. Levy and C. B. Honsberg, "Analysis of tandem solar cell efficiencies under AM1. 5G spectrum using a rapid flux calculation method," Progress in photovoltaics: Research and Applications, vol. 16(3), pp. 225-233, 2008.
A. Kuddus, A. Bakar, M. Ismail and J. Hossain, "Design of a highly efficient CdTe-based dual-heterojunction solar cell with 44% predicted efficiency," Solar Energy Volume, vol. 221, pp. 488-501, 2021 June.
A. Martí and A. Luque, "Three-terminal heterojunction bipolar transistor solar cell for high-efficiency photovoltaic conversion," Nature communications, vol. 6902, p. 6(1), 2015.
A. T. Abir, A. Joy, B. K. Mondal and J. Hossain, "Numerical prediction on the photovoltaic performance of CZTS-based thin film solar cell," Nano select, vol. 4(1), pp. 112-22, 2023 Jan.
M. A. Sayeed and H. K. Rouf, "Numerical simulation of thin film solar cell using SCAPS-1D: ZnSe as window layer," in In 2019 22nd International Conference on Computer and Information Technology (ICCIT) (pp. 1-5). IEEE, Dhaka, Bangladesh, 2019, December.
A. Cherouana and R. Labbani, "Numerical simulation of CZTS solar cell with silicon back surface field," Materials Today: Proceedings, vol. 5(5), pp. 13795-13799, 2018.
Y. H. Khattak, F. Baig, B. Marí, S. Beg, S. R. Gillani and T. Ahmed, "Effect of CdTe back surface field on the efficiency enhancement of a CGS based thin film solar cell," Journal of Electronic Materials, vol. 47(9), pp. 5183-5190, 2018.
S. Ishizuka, "CuGaSe2 thin film solar cells: challenges for developing highly efficient wide?gap chalcopyrite photovoltaics.," physica status solidi (a), vol. 216(15), p. 1800873, 2019.
J. Song, S. Li, C. Huang, T. Anderson and O. Crisalle, "Modeling and simulation of a CuGaSe/sub 2//Cu(In/sub 1-x/,Ga/sub x/)Se/sub 2/ tandem solar cell," in 3rd World Conference onPhotovoltaic Energy Conversion, 2003. Proceedings of, Osaka, Japan, 2003, pp. 555-558 Vol.1., Osaka, Japan, 2003.
A. M. E. Raj, S. M. Delphine, C. Sanjeeviraja and a. M. Jayachandran, "Growth of ZnSe thin layers on different substrates and their structural consequences with bath temperature," Physica B: Condensed Matter, vol. 405(10), p. 2485–2491, 2010.
E. R. Shaaban, "Optical constants and fitted transmittance spectra of varies thickness of polycrystalline ZnSe thin films in terms of spectroscopic ellipsometry," Journal of alloys and compounds, vol. 563, pp. 274–279,, 2013.
L. Yang, J. Zhu and a. D. Xiao, "Microemulsion-mediated hydrothermal synthesis of ZnSe and Fe-doped ZnSe quantum dots with different luminescence characteristics," RSC advances, vol. 2(21), p. 8179–8188, 2012.
B. K. Mondal, S. K. Mostaque, M. A. Rashid, A. Kuddus, H. Shirai and a. J. Hossain, "Effect of CdS and In3Se4 BSF layers on the photovoltaic performance of PEDOT: PSS/n-Si solar cells: Simulation based on experimental data," Superlattices and Microstructures , vol. 152, p. 106853, 2021.
F. Javed, "Impact of Temperature & Illumination for Improvement in Photovoltaic System Efficiency," International Journal of Smart Grid - ijSmartGrid, vol. 6(1), pp. 19-29, 2022.
M. Dey, N. K. Das, M. Dey, S. F. U. Farhad, M. A. Matin and N. Amin, "Impact of Source to Substrate Distance on the Properties of Thermally Evaporated CdS Film," International Journal of Renewable Energy Research (IJRER), vol. 11(1), pp. 495-503, 2021.
V. G. Rajeshmon, N. Poornima, C. S. Kartha and K. P. Vijayakumar, "Modification of the optoelectronic properties of sprayed In2S3 thin films by indium diffusion for application as buffer layer in CZTS based solar cell," Journal of alloys and compounds, vol. 553, pp. 239-244, 2013 Mar.
P. Prabeesh, V. G. Sajeesh, I. P. Selvam, M. S. D. Bharati, G. M. Rao and S. N. Potty, "CZTS solar cell with non-toxic buffer layer: A study on the sulphurization temperature and absorber layer thickness," Solar Energy, vol. 207, pp. 419-427, 2020.
F. Jiang, C. Ozaki, Gunawan, T. Harada, Z. Tang, T. Minemoto, Y. Nose and S. Ikeda, "Effect of indium doping on surface optoelectrical properties of Cu2ZnSnS4 photoabsorber and interfacial/photovoltaic performance of cadmium free In2S3/Cu2ZnSnS4 heterojunction thin film solar cell," Chemistry of Materials, vol. 28(10), pp. 3283-3291, 2016.
M. D. Wanda, S. Ouédraogo and J. M. B. Ndjaka, "Theoretical analysis of minority carrier lifetime and Cd-free buffer layers on the CZTS based solar cell performances," Optik, vol. 183, pp. 284-293, 2019.
R. Mannu, S. Padhy and U. P. Singh, "Variation of different layer parameters in a CZTS based solar cell for optimum performance: A simulative approach," Materials Today: Proceedings, vol. 39, pp. 1876-1883, 2021.
M. A. Ashraf and I. Alam, "Numerical simulation of CIGS, CISSe and CZTS-based solar cells with In2S3 as buffer layer and Au as back contact using SCAPS 1D," Engineering Research Express, vol. 2(3), p. 035015, 2020.
A. Srivastava, P. Dua, T. R. Lenka and S. K. Tripathy, "Numerical simulations on CZTS/CZTSe based solar cell with ZnSe as an alternative buffer layer using SCAPS-1D," Materials Today: Proceedings, vol. 43, pp. 3735-3739, 2021.
M. A. Shafi, L. Khan, S. Ullah, M. Y. Shafi, A. Bouich, H. Ullah and B. Mari, "Novel compositional engineering for~ 26% efficient CZTS-perovskite tandem solar cell," Optik, vol. 253, p. 168568, 2022.
DOI (PDF): https://doi.org/10.20508/ijsmartgrid.v8i3.349.g358
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